Hello Edward.
I think, the former owner of Your horn was a person who didnt like his/her instrument. He/she never watched to it and I am asure, it never was cleaned up inside.
Valve repair is a difficult thing. If the brown/green coating (patina) will be smooth or polished off form the contact surface, the valves loose thightness.
Inside the valveopenings (aircanals) You can polish it.
If the upper bearings (at the valvehead) are wear off, its possible, to repair it. The upper bearings will be jolt and with polishpaste You smooth it until it will fit (will need some hours!) Smooth it by HAND! NEVER use a drillmachine! It wobbles! And so the bearing is not 100% straight. For this work, You can buy a special handcrank (e.g. at "Ferro tools").
If You can move the valve up and down in its casing, You have to put the lower bearingplate on the lathe and turn the rabbet some /100 Millimeter deeper. If it has no rabbet, reduce its diameter step by step. So it goes deeper into the caseing and the differnce is off.
If the lower bearing is wear off, turn a new bearingplate (bearingcap) on the lathe.
You wrote, that one valve will not turn 90°. May be, the valve (the upper bearingpivot) is bent. It is possible, to hammer it straight. But thats not possible, if the valve is made from castbrass! It will break under the hammer! Or there is a little burr at the lower bearingplate or inside the case or at the valvebody.
Further You wrote, that green slime is at the valveports. If You will clean up Your horn inside all six month, You never will have mud inside. But for a complete cleaning, You have to remove the valves. Use a cleaning-set like "Reka". (If You can not buy it in America, please contact me.) Things like HW-Brass safer are not strong enough to remove old mud. If the mud is so strong, that You need a file, forget it! Take a fexible cleaner with a brassbrush into a drillmachine, put some dishes cleaning solvent on it and mill the mud out. Clean up the horn with a lot of water, because the rests of the solvent/mud will become lumpy.
And if You grease Your slides, never push the old grease into the valves. Its residue become lumpy and the valve will stock. (Use Hetman No 7.)
But I have a question: In America, string action is favored. How is it possible, that the valves are so bad after only 20 years of use? At the string action, the leverpower is very equal and its influence to the bearings is not as strong as at a connection by rods.
Are the valvecasings made from brass or from nickelsilver? What kind of horn is it (mark or model)?
I hope, You will understand, what I mean, because my english is very bad!
Regards, Martin